Diffusion frequency factors in some simple examples of transition-state rate theory.
نویسندگان
چکیده
منابع مشابه
Diffusion frequency factors in some simple examples of transition-state rate theory.
In the Eyring rate theory, the rate constant is expressed as a product of a frequency factor (kT/h) and a quotient of partition functions. Continuing an earlier paper, it is shown here by means of simple examples that the Eyring formalism may be extended to include diffusion-controlled processes if a new frequency factor, D/Rlambda, is substituted for kT/h, where D = diffusion coefficient, lamb...
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ژورنال
عنوان ژورنال: Proceedings of the National Academy of Sciences
سال: 1976
ISSN: 0027-8424,1091-6490
DOI: 10.1073/pnas.73.3.679